品牌 | 货号 | 期货/现货 | 规格 | 价格 | 数量 |
---|---|---|---|---|---|
阿拉丁 | B130058-100ml | 期货 | 100ml | 313.9 |
|
阿拉丁 | B130058-500ml | 期货 | 500ml | 1172.9 |
|
阿拉丁 | B130058-1L | 期货 | 1L | 1949.9 |
|
【9-硼双环[3.3.1]壬烷】
规格或纯度: 0.5 M in THF
CAS编号: 280-64-8(THF)
分子式: C8H15B
分子量: 122.02
Beilstein号: 605509
MDL号: MFCD00074742
PubChem编号: 6327450
别名 | 9-硼双环[3.3.1]壬烷溶液| |
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英文别名 | 9-Borabicyclo[3.3.1]nonane|280-64-8|9-BBN|9-Borabicyclo(3.3.1)nonane|9-Borabicyclo(3,3,1)nonane|4K4J8L1OG9|9-borabicyclo(3.3.1]nonane|9-borabicyclo[3,3,1]nonane|EINECS 206-000-9|9-borabicyclo[3.3.1]nonan|MFCD00074742|9$l^{2}-borabicyclo[3.3.1]nonane|UNII- |
规格或纯度 | 0.5 M in THF |
英文名称 | 9-Borabicyclo[3.3.1]nonane |
应用 | 烯烃保护基团? 反应物用于: · 线性SPPS合成泛素衍生物 · 铜催化有机硼化合物与伯烷基卤化物和拟卤化物发生交叉偶联反应 · 将烯烃分子内插入钯-氮键 · 制备(膦酰基乙酰基)鸟氨酸以研究对酵母中精氨酸生物合成基因的影响 · Hetero-Diels-Alder反应合成螺环生物碱 使用 9-BBN 对相应环状缩醛进行还原以鉴别对称二醇。 选择性硼氢化还原试剂。 |
储存温度 | 充氩 |
运输条件 | 常规运输 |
产品介绍 | 烯烃保护基团† 反应物用于: · 线性SPPS合成泛素衍生物 · 铜催化有机硼化合物与伯烷基卤化物和拟卤化物发生交叉偶联反应 · 将烯烃分子内插入钯-氮键 · 制备(膦酰基乙酰基)鸟氨酸以研究对酵母中精氨酸生物合成基因的影响 · Hetero-Diels-Alder反应合成螺环生物碱 使用 9-BBN 对相应环状缩醛进行还原以鉴别对称二醇。 选择性硼氢化还原试剂。 9-Borabicyclo[3.3.1]nonane is an organic compound, which is generally used as a hydroborating agent. It is thermally stable, less sensitive to oxygen and water when compared to other dialkyl boranes. It is commonly used to prepare aldehydes from alkynes. Differentiation of symmetrical diols by reduction of the corresponding cyclic acetals with 9-BBN. 9-Borabicyclo[3.3.1]nonane is an organic compound, which is generally used as a hydroborating agent. It is thermally stable, less sensitive to oxygen and water when compared to other dialkyl boranes. It is commonly used to prepare aldehydes from alkynes. application: 9-BBN monomer acts as a selective hydroboration reagent in synthetic organic chemistry. It is employed in Suzuki reactions as well as in the preparation of terminal alcohols by the region selective addition of alkenes followed by oxidative cleavage using hydrogen peroxide. It is also used in copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides. It acts as a protecting group for alkenes. Further, it is used as a reactant for Hetero-Diels-Alder reaction for the synthesis of spirocyclic alkaloids. In addition to this, it is used in intramolecular insertion of alkenes into palladium-nitrogen bonds. |
溶解性 | Miscible with ether, hexane, benzene, toluene, carbon tetrachloride, chloroform, dimethylsulfide and dichloromethane. Slightly miscible with cyclohexane, dimethoxyethane, diglyme and dioxane. |
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密度 | 0.884 |
敏感性 | 对空气和水分敏感 |
象形图 | Health Hazard Harmful Flammable |
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信号词 | Danger |
危险声明 | H319: Causes serious eye irritation H335: May cause respiratory irritation H260: In contact with water releases flammable gases which may ignite spontaneously H225: Highly Flammable liquid and vapor |
预防措施声明 | P261,P223,P231+P232,P370+P378,P422,P210 |
WGK Germany | 3 |